Product ID:LACTOL SPIRITS 2006
MSDS Date:12/16/1996
FSC:6810
NIIN:00-238-8117
Status Code:A
MSDS Number: CJGPS

UNION OIL COMPANY OF CALIFORNIA

1701 GOLF ROAD,SUITE 1-1101
ROLLING MEADOWS, IL 60008-4295
US

Emergency Phone: 800-967-7601

Info Phone: 800-967-7601

Cage: TO018

UNION OIL COMPANY OF CALIFORNIA

ROLLING MEADOWS, IL 60008-4295 US

Telephone: 800-967-7601

Cage: TO018

LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM)

CAS: 64742-89-8

METHYLCYCLOHEXANE

CAS: 108-87-2

RTECS: GV6125000

OSHA PEL 2000 MG/M3;500 PPM

ACGIH TLV: 1610 MG/M3;400 PPM

N-HEPTANE

CAS: 142-82-5

RTECS: MI7700000

OSHA PEL 2000 MG/M3;500 PPM

ACGIH TLV: 1640 MG/M3;400 PPM

TOLUENE

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL 100 PPM

ACGIH TLV: 188 MG/M3;50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CYCLOHEXANE

CAS: 110-82-7

RTECS: GU6300000

OSHA PEL 1050 MG/M3;300 PPM

ACGIH TLV: 1030 MG/M3;300 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

OTHER C6-C8 PARAFFINS AND CYCLOPARAFFINS

BENZENE

CAS: 71-43-2

RTECS: CY1400000

OSHA PEL see 1910.1028

ACGIH TLV: 32 MG/M3;10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:TARGET ORGANS: CENTRAL NERVOUS SYSTEM,
LIVER, KIDNEY AND SENSE OF HEARING. ACUTE - EYE: EYE IRRITATANT.
CONTACT MAY CAUSE STINGING, WATERING, REDNESS, AND SWELLING. SKIN:
SKIN IRRITANT. CONTACT MAY C AUSE REDNESS, BURNING, DRYING AND
CRACKING OF THE SKIN, AND SKIN DAMAGE. SKIN ABSORBTION IS SLIGHT.
INGESTION: LOW TO MODERATE DEGREE OF TOXICITY BY INGESTION.
ASPIRATION HAZARD - THIS MATERIAL CAN EN TER LUNGS DURING
SWALLOWING OR VOMITING AND CAUSE LUNG INFLAMMATION AND DAMGE.
INHALATION: LOW TO MODERATE DEGREE OF TOXICITY BY BY INHALATION.
CHRONIC - MAY CAUSE LIVER AND KIDNEYS EFFECTS, PERMANENT BRAIN AND
NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:CONTAINS BENZENE.
Effects of Overexposure:SEVERE IRRITATION, HEADACHE, DIZZINESS, NAUSEA,
VOMITING, DROWSINESS, COMA, EYE REDNESS, TEARNING, BLURRED VISION,
SKIN CRACKING, DEFATTING, DRYING, UNCONSCIOUSNESS, WEAKNESS,
PULMONARY EDEMA, FATIGUE , DIARRHEA
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS, OR IMPAIRED CENTRAL NERVOUS SYSTEM, LIVER,
KIDNEY, HEART, OR RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO
THE EFFECTS OF THIS PRODUCT.

First Aid:INHALATION: MOVE VICTIM TO FRESH AIR. IF BREATHING IS
DIFFICULT, PROVIDE OXYGEN. IF NOT BREATHING, BEGIN ARTIFICIAL
RESPIRATION. SEEK MEDICAL ATTENTION. EYE: MOVE VICTIM TO FRESH
AIR. FLUSH EYE WITH CLEAN WATER. FOR DIRECT CONTACT, HOLD EYELIDS
APART AND FLUSH AFFECTED EYE WITH WATER FOR AT LEAST 15 MINUTES.
SEEK MEDICAL ATTENTION. SKIN: FLUSH WITH PLENTY OF WATER. IF SKIN
IS DAMAGED, APPLY A DRE SSING AND SEEK MEDICAL ATTENTION.
INGESTION: SEEK MEDICAL ATTENTION. IF INDIVIDUAL IS DROWSY OR
UNCONSCIOUS, PLACE INDIVIDUAL ON LEFT SIDE WITH HEAD DOWN. CONTACT
A PHYSICIAN AT ONCE. IF CONSCIOUS AND LARGE AMOUNTS INGESTED,
INDUCE VOMITING

Flash Point Method:TCC
Flash Point:=-6.7C, 20.F
Autoignition Temp:=304.4C, 580.F
Lower Limits:1.0
Upper Limits:7.0
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, SAND, FOAM/DRY
CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS
COOL. CARBON DIOXIDE CAN DISPLACE OXYGEN. USE CAUTION IN CONFINED
AREA.
Fire Fighting Procedures:WEAR BUNKER GEAR AND SELF CONTAINED BREATHING
APPARATUS IF FIRE BEYOND INCIPIENT STAGE. WEAR OTHER APPROPRIATE
PROTECTIVE EQUIPMENT. ISOLATE DANGER AREA. USE WATER SPRAY TO
MINIMIZE OR DISPERSE VAPORS . AVOID SPREADING BURNING LIQUID WITH
WATER USED FOR COOLING PURPOSES.
Unusual Fire/Explosion Hazard:FLAMMABLE. VAPOR TRAVELS DISTANCES TO
IGNITION SOURCE CAUSING IT TO IGNITE, FLASHBACK OR EXPLODE. VAPORS
HEAVIER THAN AIR CAN ACCUMULATE IN LOW AREAS. IF CONTAINER IS NOT
COOLED PROPERLY, IT CAN RUPTU RE IN THE HEAT OF FIRE.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES
OF IGNITION. VENTILATE AREA. STOP SPILL IF POSSIBLE WITHOUT RISK.
BLANKET SPILL WITH ALCOHOL-TYPE AQUEOUS FILM-FORMING FOAM OR USE
WATER SPRAY TO DISPERSE VAPORS. CONTAIN AND PICK UP WITH
NON-FLAMMABLE ABSORBENT SUCH AS SAND OR USE EXPLOSION-PROOF PUMP.
PREVENT LIQUID FROM ENTERING SEWERS, WATERWAYS, CONFINED SPACES.
REPORT IF REQUIRED 800-424-8802.

Handling and Storage Precautions:OPEN CONTAINER SLOWLY TO RELIEVE ANY
PRESSURE. STORE IN COOL, VENTILATED PLACE. KEEP CONTAINER TIGHTLY
CLOSED. STORE IN ACCORDANCE WITH NATIONAL FIRE PROTECTION
ASSOCIATION REGULATIONS. KEEP AWAY FROM IGNITION SOURCES, AND
INCOMPATIBLES. CONTAINERS SHOULD BE BOUNDED AND GROUNDED FOR
TRANSFERS.
Other Precautions:FLAMMABLE. EMPTY CONTAINERS RETAIN PRODUCT RESIDUES
(VAPORS, LIQUID) AND CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT,
WELD, BRAZE, SOLDER OR DRILL. KEEP OUT OF REACH OF CHILDREN. AVOID
BREATHING VAPORS. DO NOT GET IN EYE, ON SKIN OR ON CLOTHING. AVOID
INGESTION. DESTROY CONTAMINATED LEATHER CLOTHING.

Respiratory Protection:NIOSH/MSHA AIR PURRIFYING RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGE MAY BE USED IFAIRBORNE CONCENTRATION ARE
EXPECTED TO EXCEED EXPOSURE LIMITS. USE POSITIVE PRESSURE AIR
SUPPLIED RESPIRATOR WHERE THERE IS POTENTIAL FOR UNCONTROLED
RELEASE, PEL ARE N/KNOWN, OR OTHER CIRCUMSTANCES WHERE AIR
PURIFYING RESPIRATOR MAY NOT PROVIDE ADEQUATE PROTECTION.
Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:IMPERMEABLE TO THE SPECIFIC MATERIAL HANDLED.
Eye Protection:APPROVED EYE PROTECTION TO SAFEGUARD AGAINST POTENTIAL
EYE CONTACT.
Other Protective Equipment:EYE-WASH AND QUICK DRENCH SHOWER FACILITIES
SHOULD BE AVAILABLE IN WORK AREA.
Work Hygienic Practices:THOROUGHLY CLEAN SHOES AND WASH CONTAMINATED
CLOTHING BEFORE REUSE. IT IS RECOMMENDED THAT IMPERVIOUS CLOTHING
BE WORN.
Supplemental Safety and Health

HCC:F2
Boiling Pt:=93.9C, 201.F
B.P. Text:201-255F
Melt/Freeze Pt:M.P/F.P Text:NO DATA
Vapor Pres:25MMHG
Vapor Density:3.40 AIR=1
Spec Gravity:0.75 60F
VOC Pounds/Gallon:745
Viscosity:0.68CST
Evaporation Rate & Reference:3.90 NBUAC=1
Solubility in Water:0.02 %
Appearance and Odor:WATER-SHITE LIQUID WITH LIGHT HYDROCARBON ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS AND REDUCING AGENTS.
Stability Condition to Avoid:FLAMM LIQUID AND VAPOR. VAPOR CAN CAUSE
FLASH FIRE. AVOID ALL POSSIBLE SOURCES OF IGNITION (SEE FIRE
FIGHTING & HANDLING AND STORAGE SECTIONS.)
Hazardous Decomposition Products:COMBUSTION CAN YIELD CARBON DIOXIDE
AND CARBON MONOXIDE.

Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL,
STATE, AND FEDERAL LAWS AND REGULATIONS. RCRA HAZARDOUS WASTE
NUMBERS: D001 AND D015 (OR K005 IF SPENT) THIS WASTE IS SUBJECT TO
LAND DISPOSAL RESTRICTIONS I N 40 CFR 268.40 AND MAY REQUIRE
TREATMENT PRIOR TO DISPOSAL EMPTY DRUMS SHOULD BE RETURNED TO
DISTRI BUTOR OR A DRUM RECONDITIONER.

Toxicological Information:TOLUENE. TARGET ORGAN(S): INTENTIONAL MISUSE
BY DELIBERATE INHALATION OF HIGH CONCENTRATIONS OF TOLUENE HAS BEEN
SHOWN TO CAUSE LIVER, KIDNEY AND CENTRAL NERVOUS SYSTEM DAMAGE,
INCLUDING HEARING LOSS AND VISUAL DISTURBANCES. DEVELOPMENTAL:
EXPOSURE TO TOLUENE DURING PREGNANCY HAS DEMONSTRATED LIMITED
EVIDENCE OF DEVELOPMENTAL TOXICITY IN LABORATORY ANIMALS. THE
EFFECTS SEEN INCLUDE DECREASED FETAL BODY WEIGHT AND INCREASED
SKELETAL VARIATIONS IN BOTH INHALATION AND ORAL STUDIES.

SARA Title III Information:THIS PRODUCT CONTAINS THE FOLLOWING
CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF
TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
(SARA) OF 1986 AND 40 CFR PART 372: TOLUENE AND CYCLOHEXANE
Federal Regulatory Information:EPA (CERCLA) REPORTABLE QUANTITY: RQ # 1
TOLUENE 1000 LB EQUAL TO 5556 LB, (896 GAL), OF THIS MATERIAL. RQ
# 2 CYCLOHEXANE 1000 LB EQUAL TO 33333 LB, (5376 GAL), OF THIS
MATERIAL.
State Regulatory Information:THIS PRODUCT CONTAINS THE FOLLOWING
CHEMICALS WHICH ARE KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM, AND ARE SUBJECT
TO THE REQUIREMENTS OF CALIFORNIA PR OPOSITION 65 (CA HEALTH &
SAFETY CODE SECTION 25249.5): BENZENE CANCER., TOLUENE
DEVELOPMENTAL TOXICANT.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.